Journal of Petrology

A Stable Isotope Study of Anorogenic Magmatism in East Central Asia

Stephen M. Wickham , Amy D. Alberts , Ada N. Zanvilevich , Boris A. Litvinovsky, Ilya N. Bindeman, and Edwin A. Schauble

ABSTRACT

A stable isotope study of 168 plutonic igneous rock and 5 water samples from Transbaikalia, East Asia has been made, including 318 whole rock and mineral 18O/16O analyses and 14 D/H analyses. This represents the first detailed isotopic study of the enormous Phanerozoic K-rich (mostly anorogenic) granitoid belts of this region which are thousands of kilometers in length and span an age range of >250 Ma. Of the five main intrusive suites, emplacement of the youngest (Permo-Triassic) was accompanied by intense meteoric-hydrothermal activity, locally causing extreme 18O-depletion (d18Ofeldspar < -12). This reflects the very low d18O of the water involved in these systems, which probably had d18O < -20 and dD < -150, consistent with the high paleolatitude of Transbaikalia in the early Mesozoic (~80°ree;N). Despite local post-emplacement, hydrothermal 18O-depletion effects near Permo-Triassic and younger plutons, the variation of magmatic isotopic composition in the five intrusive suites, in space and time, can be clearly discerned using the 18O/16O variation in phases such as quartz and sphene that are resistant to sub-solidus exchange. A procedure for analyzing 18O/16O in sphene using a laser fluorination technique is described: analysis of samples as small as 0.4 mg (including single crystals of sphene from granitoids) is possible and provides an effective way to estimate the magmatic d18O value of plutonic igneous rocks. Most sphene and quartz d18O values vary by 1.0 to 2.0%o within each of the five main intrusive suites in Transbaikalia (ranging in age from mid-Paleozoic to Mesozoic) and are uniform both within individual plutons and among plutons of the same suite separated by tens or hundreds of kilometers. However, each suite has a unique range in 18O/16O, indicating that on a regional scale, the magmatic d18O values of these granitoids decreased progressively in ~1 per mil decrements from ~+10 in the earliest group to ~+6 in the youngest. This progression was accompanied by increases in the concentration of elements such as K and Zr, and decreases in the concentration of elements such as Sr and B. These systematics require large-scale deep crustal melting and mixing processes in order to generate the compositional uniformity of individual plutons and groups over such wide areas, and also a progressive hybridization of the crust with alkalic, mantle-derived magmas in order to generate syenites and granites with progressively lower d18O values. This process may be a hallmark of anorogenic granitoid petrogenesis and the intracontinental cratonization process in general, and also represents an important (though largely cryptic) crustal growth mechanism.

Key words

anorogenic granitoids;crustal growth;hybridization;hydrothermal systems;stable isotopes

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