Journal of Petrology


Kiglapait Mineralogy III: Olivine Compositions and Rayleigh Fractionation Models

S.A. Morse


ABSTRACT

Olivines, present throughout the layered cumulates of the Kiglapait Intrusion, record extreme iron enrichment during fractional crystallization. Mn is less compatible than Fe; the exchange coefficient KD for MnFe -1 (OL-LIQ) has values near 0.95 but they drop to 0.7 near the Lower Zone/Upper Zone boundary. Ca is depleted by more than a factor of 30 relative to experimental values at 5 kb pressure. Attempts to find a sink for Ca in the Lower Zone without invoking liquid as a reactant are unconvincing, and questions of metastability arise.

Cumulus olivines vary systematically to lower Fo contents with stratigraphic height. Using equilibrium values for the exchange coefficient KD (FeMg -1, OL-LIQ), and the observed mode of olivine and residual porosity, a Rayleigh fractionation calculation reproduces the observed Lower Zone trend without recourse to multiple injections of magma. An anomalously Fe-rich region above the Main Ore Band in the Upper Zone is ascribed to ponding of Fe-rich magma at the floor of the intrusion until later, buoyant residual magma entrained the Fe-rich residua. Such Fe-rich ponds probably account for the abnormal Fe enrichment shown by some other Fenner-trend layered intrusions.

Summation over the observed crystal compositions yields values of XMg that do not represent the equilibrium liquid, but that reduce to it by a simple multiplier p = 0.78. This result means that if KD is known, the high temperature, liquidus olivine compositions can be retrieved, or vice-versa. Because the observed olivine compositions are supported by realistic forward models, there is no need to invoke evolved boundary-layer liquids to explain the in situ crystallization of Kiglapait cumulates. Classical cumulate theory suffices.

Keywords

olivine;Rayleigh fractionation;Kiglapait Intrusion;cumulate theory

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