Oxygen isotopic analyses indicate that Unit II has experienced extensive crustal contamination. d18O values of Unit II range from 6.9 to 7.1 %o and are 18O enriched compared to values of 5.1 to 6.8 found in other units. Silica contamination is indicated based not only on d18O values, but also by the predominance of orthopyroxene in the unit. Possible high-18O contaminant rocks include the Giants Range Batholith and pelitic rocks of the Lower Proterozoic Virginia Formation or Biwabik Iron Formation.
Mass balance computations suggest that units in the Spruce Road area may be related through varying degrees of fractionation of a high-Al, olivine tholeiite magma. Modelling of trace element concentrations and variations in mineral chemistry suggest that discontinuities within the major units developed by in situ boundary layer equilibrium crystallization of solidification zones ~20 to 50 meters in thickness, followed by recharge of fresh magma. Upward enrichment of incompatible elements, olivine Fa content, and plagioclase Ab content may be effectively explained by this process. d18O values of uncontaminated rock types are strongly correlative with modal mineralogy, and can also be modelled by boundary layer fractionation. A parental magma d18O value of ~6.3%o is calculated for Unit VII based on olivine and plagioclase values, and is similar to that of several other large, layered mafic intrusives.
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