Journal of Physical Chemistry A, 2003, V 107, N 50, December 18.


ARTICLES

DYNAMICS AND RELAXATION
Ultrafast Vibrational and Thermal Relaxation of Dye Molecules in Solutions Jian-Yong Liu, Wen-Hui Fan, Ke-Li Han, Wei-Qiao Deng, Da-Li Xu, and Nan-Quan Lou pp 10857 - 10861; Surface Coverage Effects on the Formation of Molecular Hydrogen on a Graphite Surface via an Eley-Rideal Mechanism Anthony J. H. M. Meijer, Andrew J. Fisher, and David C. Clary pp 10862 - 10871; Dynamics of Molecules near Ionization Theis I. Slling, Carsten Kotting, and Ahmed H. Zewail pp 10872 - 10887; Photodissociation Dynamics of Allyl Alcohol at 193 nm Tae Yeon Kang, Seung Keun Shin, and Hong Lae Kim pp 10888 - 10892; Reactivity of the Ground and Excited Spin-Orbit States for the Reaction of the F(2P3/2,2P1/2) with D2 Yan Zhang, Ting-Xian Xie, and Ke-Li Han pp 10893 - 10896; Femtosecond Photoelectron Imaging on Pyridine: Ultrafast Electronic Dephasing from the S1(n*) State and Rydberg State Energetics Masaaki Tsubouchi and Toshinori Suzuki pp 10897 - 10903;
SPECTROSCOPY, GASEOUS CLUSTERS, AND MOLECULAR BEAMS
Size-Dependent Reaction Cross Section of Protonated Water Clusters H+(H2O)n (n = 2-11) with D2O Satoru Yamaguchi, Satoshi Kudoh, Yoshiki Okada, Takaaki Orii, Kazuo Takeuchi, Takashi Ichikawa, and Hiromi Nakai pp 10904 - 10910; Structural Ambiguities Revisited in Two Bridged Ring Systems Exhibiting Enantiotopic Elements, Using Natural Abundance Deuterium NMR in Chiral Liquid Crystals Christie Aroulanda, Philippe Lesot, Denis Merlet, and Jacques Courtieu pp 10911 - 10918; Laboratory Infrared Observation of Linear C7S Carbon-Sulfur Cluster in Solid Argon Haiyan Wang, Jan Szczepanski, Philip J. Brucat, and Martin T. Vala pp 10919 - 10925; Nascent versus "Steady-State" Rovibrational Distributions in the Products of the O(3P) + O3(1A) Reaction P. J. S. B. Caridade, J. L. Llanio-Trujillo, and A. J. C. Varandas pp 10926 - 10932; High-Field/High-Frequency ESR Study of Gd@C82-I Ko Furukawa, Shingo Okubo, Haruhito Kato, Hisanori Shinohara, and Tatsuhisa Kato pp 10933 - 10937; Does PRODAN Possess a Planar or Twisted Charge-Transfer Excited State? Photophysical Properties of Two PRODAN Derivatives Bethany C. Lobo and Christopher J. Abelt pp 10938 - 10943; Photolysis of Matrix Isolated HONO/SO2 System. Identification and Infrared Spectra of Nitrososulfonic Acid HO(NO)SO2 and Hydroxysulfonyl HOSO2 Radical M. Wierzejewska and A. Olbert-Majkut pp 10944 - 10952; DFT Studies of the Resonance Raman Spectra of Ground and Excited Triplet State Free Base meso-Tetraphenylporphyrin (H2TPP) Roma E. Oakes and Steven E. J. Bell pp 10953 - 10959; Rotationally Resolved (1 + 1') Resonance-Enhanced Multiphoton Ionization (REMPI) of CaR (R = H, D) in Supersonic Beams: CaR X 2+ (' ' = 0) CaR* B 2+ (' = 0, 1) CaR+ X 1+ Khaled Gasmi, Reem M. Al-Tuwirqi, Stefan Skowronek, Helmut H. Telle, and Angel Gonzalez Urena pp 10960 - 10968; Vibrational Analysis of Vacuum Ultraviolet Mass-Analyzed Threshold Ionization Spectra of Phenylacetylene and Benzonitrile Chan Ho Kwon, Hong Lae Kim, and Myung Soo Kim pp 10969 - 10975; Dissociation of SO42-(H2O)n Clusters, n = 3-17 Richard L. Wong and Evan R. Williams pp 10976 - 10983; Discrimination of Rotational Isomers of 2-Phenylethanol by Dispersed Fluorescence Spectroscopy Sujit S. Panja and Tapas Chakraborty pp 10984 - 10987;
KINETICS; ATMOSPHERIC AND ENVIRONMENTAL PHYSICAL CHEMISTRY
Measurements of High-Temperature Silane Pyrolysis Using SiH4 IR Emission and SiH2 Laser Absorption Eric L. Petersen and Mark W. Crofton pp 10988 - 10995; High Temperature Reaction of S + SO2 SO + SO: Implication of S2O2 Intermediate Complex Formation Yoshinori Murakami, Shouichi Onishi, Takaomi Kobayashi, Nobuyuki Fujii, Nobuyasu Isshiki, Kentaro Tsuchiya, Atsumu Tezaki, and Hiroyuki Matsui pp 10996 - 11000; Identification of the CH + O2 OH(A) + CO Reaction as the Source of OH(A-X) Chemiluminescence in C2H2/O/H/O2 Atomic Flames and Determination of Its Absolute Rate Constant over the Range T = 296 to 511 K S. A. Carl, M. Van Poppel, and J. Peeters pp 11001 - 11007; Meandering Spiral Waves in the 1,4-Cyclohexanedione Belousov-Zhabotinsky System Catalyzed by Fe[batho(SO3)2]34-/3- Niklas Manz, Brent T. Ginn, and Oliver Steinbock pp 11008 - 11012; Experimental Study of NO Reaction with Isoprene Hydroxyalkyl Peroxy Radicals Dan Zhang, Renyi Zhang, and Simon W. North pp 11013 - 11019; Experiments and Calculations on Rate Coefficients for Pyrolysis of SO2 and the Reaction O + SO at High Temperatures Chih-Wei Lu, Yu-Jong Wu, Yuan-Pern Lee, R. S. Zhu, and M. C. Lin pp 11020 - 11029; Adsorption of Gas-Phase Nitric Acid to n-Hexane Soot: Thermodynamics and Mechanism Daniel G. Aubin and Jonathan P. Abbatt pp 11030 - 11037; Direct Observation of the Kinetics of an Atmospherically Important Reaction at the Air-Aqueous Interface Baagi T. Mmereki and D. J. Donaldson pp 11038 - 11042; ion of Hydrogen from Methanol by Hydroxyl Radical in Subcritical and Supercritical Water Junbo Feng, Sudhir N. V. K. Aki, John E. Chateauneuf, and Joan F. Brennecke pp 11043 - 11048; Investigation of the Prototype Silylene Reaction, SiH2 + H2O (and D2O): Time-Resolved Gas-Phase Kinetic Studies, Isotope Effects, RRKM Calculations, and Quantum Chemical Calculations of the Reaction Energy Surface Rosa Becerra, J. Pat Cannady, and Robin Walsh pp 11049 - 11056; Master Equation Models for the Pressure- and Temperature-Dependent Reactions HO + NO2 HONO2 and HO + NO2 HOONO David M. Golden, John R. Barker, and Lawrence L. Lohr pp 11057 - 11071; Formation of Hydrogen Peroxide in Photocatalytic Reactions Fumihide Shiraishi, Tsugunori Nakasako, and Zhaozhe Hua pp 11072 - 11081; Isodesmic Reactions for Transition States: Reactions of Cl Atoms with Methane and Halogenated Methanes Vadim D. Knyazev pp 11082 - 11091;
MOLECULAR STRUCTURE, BONDING, QUANTUM CHEMISTRY, AND GENERAL THEORY
Theoretical Analysis on the Fundamental and Overtone OH Stretching Spectra of Several Simple Acids and Alcohols Kaito Takahashi, Michihiko Sugawara, and Satoshi Yabushita pp 11092 - 11101; Unusual Magnetic Behavior of Six-Coordinate, Mixed-Ligand Re(II) Complexes: Origin of a Strong Temperature-Independent Paramagnetism Kim R. Dunbar, Eric J. Schelter, Andrei V. Palii, Sergei M. Ostrovsky, Vadim Yu. Mirovitskii, Joshua M. Hudson, Mohammad A. Omary, Sophia I. Klokishner, and Boris S. Tsukerblat pp 11102 - 11111; The Heterolytic Dissociation of Neutral and Protonated Nitrous Acid Hong Wu and Rainer Glaser pp 11112 - 11119; Similarity and Chirality: Quantum Chemical Study of Dissimilarity of Enantiomers Greet Boon, Christian Van Alsenoy, Frank De Proft, Patrick Bultinck, and Paul Geerlings pp 11120 - 11127; 18-Crown-6 and Its Hydrates: Bridging but Versatile Hydrogen Bonding. A Theoretical Study of Static and Dynamic Properties R. Schurhammer, P. Vayssiere, and G. Wipff pp 11128 - 11138; Can Diarylethene Photochromism Be Explained by a Reaction Path Alone? A CASSCF Study with Model MMVB Dynamics Martial Boggio-Pasqua, Marcella Ravaglia, Michael J. Bearpark, Marco Garavelli, and Michael A. Robb pp 11139 - 11152; Bond Strengths in ChCl3- and ChOCl3- (Ch = S, Se, Te): Experiment and Theory Kim C. Lobring, Changtong Hao, Jordan K. Forbes, Michael R. J. Ivanov, Steven M. Bachrach, and Lee S. Sunderlin pp 11153 - 11160; Theoretical and Electrochemical Study of the Quinone-Benzoic Acid Adduct Linked by Hydrogen Bonds Jorge Garza, Rubicelia Vargas, Martin Gomez, Ignacio Gonzalez, and Felipe J. Gonzalez pp 11161 - 11168; Ab Initio Study on Phenylacetylene in S1 and S2 Yoshiaki Amatatsu and Yasunori Hasebe pp 11169 - 11173; Ab Initio Study of the Deamination of Formamidine Christopher Flinn, Raymond A. Poirier, and W. Andrzej Sokalski pp 11174 - 11181; Phototriggered Linkage Isomerization in Ruthenium-Dimethylsulfoxyde Complexes: Insights from Theory Ilaria Ciofini, Claude A. Daul, and Carlo Adamo pp 11182 - 11190; Ab Initio Study of Aromatic Side Chains of Amino Acids in Gas Phase and Solution David M. Rogers and Jonathan D. Hirst pp 11191 - 11200; Influence of Crystal Effects on Molecular Charge Densities in a Study of 9-Ethynyl-9-fluorenol Jacob Overgaard, Mark P. Waller, and David E. Hibbs pp 11201 - 11208; Isomerization and Dissociation of CHNS: Quantum Mechanical Study Maria Wierzejewska and Jerzy Moc pp 11209 - 11216; Density Functional Theory Study of the Electronic State, Geometry, and Harmonic Frequencies for Linear CnP2 Clusters: A Comparison with CnN2 K. Chuchev and J. J. BelBruno pp 11217 - 11222; Comprehensive Model for the Electronic Structures of 1,2,4-Cyclohexatriene and Related Compounds Patrick W. Musch, Daniel Scheidel, and Bernd Engels pp 11223 - 11230;
GENERAL PHYSICAL CHEMISTRY
Effect of the Nitrogen Heteroatom on the Excited State Properties of 1,4-Distyrylbenzene E. Marri, D. Pannacci, G. Galiazzo, U. Mazzucato, and A. Spalletti pp 11231 - 11238; An FT-IR Study of Crown Ether-Water Complexation in Supercritical CO2 Anne Rustenholtz, John L. Fulton, and Chien M. Wai pp 11239 - 11244; IR Vaporization Mass Spectrometry of Aerosol Particles with Ionic Solutions: The Problem of Ion-Ion Recombination Yury Dessiaterik, Theresa Nguyen, Tomas Baer, and Roger E. Miller pp 11245 - 11252; The Free Energy of Nanobubbles in Organic Liquids Siegfried Hofinger and Francesco Zerbetto pp 11253 - 11257;
COMMENTS

Comment on "Effects of Metal Ions Distinguishing between One-Step Hydrogen- and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"5 Hong-Yu Zhang and Lan-Fen Wang pp 11258 - 11259;
ADDITIONS AND CORRECTIONS

Four-Electron Three-Center Bonding: One-Electron and Concerted Two-Electron Delocalizations into Bonding and Antibonding Molecular Orbitals Richard D. Harcourt pp 11260 - 11260;