Journal of Physical Chemistry A, 2003, V 107, N 48, December 4.


 
LETTERS

Thiophosgene, A Molecule Tailor-Made for Testing Fundamental Theoretical Concepts of Radiationless Transitions: Intramolecular Dynamics of S1 Cl2CS Takashige Fujiwara, David C. Moule, and Edward C. Lim pp 10223 - 10227; Photoinduced Electron Transfer in Bianthryl and Cyanobianthryl in Solution: The Case for a High-Frequency Intramolecular Reaction Coordinate S. A. Kovalenko, J. L. Perez Lustres, N. P. Ernsting, and W. Rettig pp 10228 - 10232;
ARTICLES

DYNAMICS AND RELAXATION
Dynamics of CHFClBr and CDFClBr Inside a Thiomethylated Cryptophane, Studied by 19F-1H CSA-DD Cross-Correlated Relaxation and 2H Quadrupolar Relaxation Measurements Jeanne Crassous and Sabine Hediger pp 10233 - 10240; Fluctuation-Dissipation Theorem for Chemical Reactions near a Critical Point James K. Baird and Yeong Woo Kim pp 10241 - 10242; Photophysics of Some Disubstituted Indoles and Their Involvements in Photoinduced Electron Transfer Reactions S. K. Pal, T. Bhattacharya, T. Misra, R. D. Saini, and T. Ganguly pp 10243 - 10249;
SPECTROSCOPY, GASEOUS CLUSTERS, AND MOLECULAR BEAMS
Time-Dependent Raman Analysis of Metal-to-Ligand Charge Transfer Excited States: Application to Radiative and NonRadiative Decay Darla Graff Thompson, Jon R. Schoonover, Cliff J. Timpson, and Thomas J. Meyer pp 10250 - 10260; Prediction of Solvent Effects on Vibrational Absorption Intensities and Raman Activities in Solution within the Polarizable Continuum Model: A Study on Push-Pull Molecules Stefano Corni, Chiara Cappelli, Mirella Del Zoppo, and Jacopo Tomasi pp 10261 - 10271; Correlation of the Vibrational Spectra of Isotopomers: Theory and Application Anan Wu and Dieter Cremer pp 10272 - 10279; The Spectroscopic Consequences of C-H··· H-Bonding: C6H6-(C4H2)n Clusters with n = 1 and 2 Christopher Ramos, Paul R. Winter, Jaime A. Stearns, and Timothy S. Zwier pp 10280 - 10287;
KINETICS; ATMOSPHERIC AND ENVIRONMENTAL PHYSICAL CHEMISTRY
Kinetics of CCN Radical Reactions with a Series of Normal Alkanes Zhiqiang Zhu, Zhiqiang Zhang, Cunshun Huang, Linsen Pei, Congxiang Chen, and Yang Chen pp 10288 - 10291; Kinetics of the Reaction of the CCl2 Biradical with Molecular Chlorine Sofya A. Kostina, Alexander A. Shestov, and Vadim D. Knyazev pp 10292 - 10295; Effects of Temperature and Ionic Strength on the Rate and Equilibrium Constants for the Reaction Iaq + I-aq I2-aq Yong Liu, Ramona L. Sheaffer, and John R. Barker pp 10296 - 10302; Guided Ion Beam and Ab Initio Studies of Platinum Chloride Cations R. Liyanage, M. L. Styles, R. A. J. O'Hair, and P. B. Armentrout pp 10303 - 10310;
MOLECULAR STRUCTURE, BONDING, QUANTUM CHEMISTRY, AND GENERAL THEORY
Spectroscopic Studies of Model Carbonyl Compounds in CO2: Evidence for Cooperative C-H···O Interactions Marc A. Blatchford, Poovathinthodiyil Raveendran, and Scott L. Wallen pp 10311 - 10323; Valence Bond Formulations of the Identity Hydrogen ion Reaction, X + H-X' X-H + X', with Reactantlike and Productlike Complexes Richard D. Harcourt pp 10324 - 10329; Structure and Dynamics of the Cd2+ Ion in Aqueous Solution: Ab Initio QM/MM Molecular Dynamics Simulation Chinapong Kritayakornupong, Kristof Plankensteiner, and Bernd M. Rode pp 10330 - 10334; Computational Study of Aluminum Chloride Activation for Toluene Chlorination S. R. Spencer, M. Zhang, and C. R. F. Lund pp 10335 - 10345; Chemical Reactivity Profiles of Two Selected Polychlorinated Biphenyls R. Parthasarathi, J. Padmanabhan, V. Subramanian, B. Maiti, and P. K. Chattaraj pp 10346 - 10352; Improved Formulas for the Calculation of the Electrostatic Contribution to the Intermolecular Interaction Energy from Multipolar Expansion of the Electronic Distribution Jean-Philip Piquemal, Nohad Gresh, and Claude Giessner-Prettre pp 10353 - 10359; Solvated Succinate Dianion: Structures, Electron Binding Energies, and Dyson Orbitals Srikanth Kambalapalli and J. V. Ortiz pp 10360 - 10369; Hydrogen and Oxygen Adsorption on Rhn (n = 1-6) Clusters Daniela S. Mainardi and Perla B. Balbuena pp 10370 - 10380; Calculations of Site-Specific CO Stretching Frequencies for Copper Carbonyls with the "Near Spectroscopic Accuracy": CO Interaction with Cu+/MFI Ota Bludsk, Martin ilhan, Dana Nachtigallova, and Petr Nachtigall pp 10381 - 10388; Cooperativity in Amide Hydrogen Bonding Chains. Relation between Energy, Position, and H-Bond Chain Length in Peptide and Protein Folding Models Nadya Kobko and J. J. Dannenberg pp 10389 - 10395; In Pursuit of the Elusive Bond-Stretch Isomers by ab Initio Methods-Benzocyclobutene, Benzo[1,2:4,5]dicyclobutadiene, and Some Related Substituted Systems Ines Despotovi, Mirjana Eckert-Maksi, Zvonimir B. Maksi, and David M. Smith pp 10396 - 10405; Effects of Hydrogen Bonding on the Acidity of Uracil Mariana Di Laudo, Sarah R. Whittleton, and Stacey D. Wetmore pp 10406 - 10413; Is the Cation/ Interaction in Alkaline-Earth-Metal Dication/Benzene Complexes a Covalent Interaction? Seiji Tsuzuki, Tadafumi Uchimaru, and Masuhiro Mikami pp 10414 - 10418; A Nonparametrized Ab Initio Determination of the Heat of Formation of Hydroxylamine, NH2OH David Feller and David A. Dixon pp 10419 - 10427; Stockholders Charge Partitioning Technique. A Reliable Electron Population Analysis Scheme to Predict Intramolecular Reactivity Sequence Ram Kinkar Roy pp 10428 - 10434; Direct ab Initio Dynamics Study of the Reaction of the Hydrogen Atom with Formyl Chloride Qian Shu Li and Qiong Luo pp 10435 - 10440; Chemistry in Stringland: One-Dimensional Complexes of Main-Group Metal Ions with the Ligands NC2nX (X = N, CH; n = 0, 1, 2, 3) Simon Petrie pp 10441 - 10449; Structure and Thermodynamics of the Tin Dichloride Dimer-A Computational Study Jack B. Levy, Gabor Jancso, and Magdolna Hargittai pp 10450 - 10455; Interactions between Neutral Molecules and Ca2+: An Assessment of Theoretical Procedures Ines Corral, Otilia Mo, Manuel Yanez, Anthony P. Scott, and Leo Radom pp 10456 - 10461; Addition Reactions of 1D and 3P Atomic Oxygen with Acetylene. Potential Energy Surfaces and Stability of the Primary Products. Is Oxirene Only a Triplet Molecule? A Theoretical Study Yvan Girard and Patrick Chaquin pp 10462 - 10470; Aromaticity vs Stoichiometry Ilie Fishtik and Ravindra Datta pp 10471 - 10476;