Journal of Physical Chemistry, 2003, V 107, N 22, 5 June


ARTICLES

DYNAMICS AND RELAXATION
Photodissociation of Methacrylonitrile at 193 nm: The CN Radical Product Channel Chang Young Oh, Seung Keun Shin, Hong Lae Kim, and Chan Ryang Park pp 4333 - 4338; Oxygenation of -Methylstyrene with Molecular Oxygen, Catalyzed by 10-Methylacridinium Ion via Photoinduced Electron Transfer Kyou Suga, Kei Ohkubo, and Shunichi Fukuzumi pp 4339 - 4346; Detailed Picosecond Kerr-Gated Time-Resolved Resonance Raman Spectroscopy and Time-Resolved Emission Studies of Merocyanine 540 in Various Solvents Andrew C. Benniston, Pavel Matousek, Iain E. McCulloch, Anthony W. Parker, and Michael Towrie pp 4347 - 4353;
SPECTROSCOPY, GASEOUS CLUSTERS, AND MOLECULAR BEAMS
Mid-Infrared Spectrum of the Gas-Phase Ethyl Peroxy Radical: C2H5OO Daisy Ann Mah, Jose Cabrera, Humberto Nation, Mauricio Ramos, Shantanu Sharma, and Scott L. Nickolaisen pp 4354 - 4359; Interpretation of Single-Crystal Vibrational Spectra and Entropy of Pyrope and Almandine Using a Rigid-Ion Lattice-Dynamical Model Carlo Maria Gramaccioli and Tullio Pilati pp 4360 - 4366; Laser-Induced Fluorescence Spectroscopy of the BaNC Free Radical in a Supersonic Jet Victor Mikhailov, Martyn D. Wheeler, and Andrew M. Ellis pp 4367 - 4372; ( Mixed-Valence Properties of an Acetate-Bridged Dinuclear Ruthenium (II,III) Complex Reiner Lomoth, Ann Magnuson, Yunhua Xu, and Licheng Sun pp 4373 - 4380; ( Binding Energies of the Neutral and Ionic Clusters of Naphthalene in Their Ground Electronic States Takashige Fujiwara and Edward C. Lim pp 4381 - 4386;
KINETICS; ATMOSPHERIC AND ENVIRONMENTAL PHYSICAL CHEMISTRY
A Detailed Mechanism of the Surface-Mediated Formation of PCDD/F from the Oxidation of 2-Chlorophenol on a CuO/Silica Surface Slawomir Lomnicki and Barry Dellinger pp 4387 - 4395; Activation of CH4 by Gas-Phase Zr+ and the Thermochemistry of Zr-Ligand Complexes P. B. Armentrout and M. R. Sievers pp 4396 - 4406; Kinetic Study and Theoretical Analysis of Hydroxyl Radical Trapping and Spin Adduct Decay of Alkoxycarbonyl and Dialkoxyphosphoryl Nitrones in Aqueous Media Frederick A. Villamena, Christopher M. Hadad, and Jay L. Zweier pp 4407 - 4414; Measurements, Theory, and Modeling of OH Formation in Ethyl + O2 and Propyl + O2 Reactions John D. DeSain, Stephen J. Klippenstein, James A. Miller, and Craig A. Taatjes pp 4415 - 4427; Spatial Periodic Perturbation of Turing Pattern Development Using a Striped Mask Igal Berenstein, Milos Dolnik, Anatol M. Zhabotinsky, and Irving R. Epstein pp 4428 - 4435; ( Raman Spectroscopy as a Probe of Low-Temperature Ionic Speciation in Nitric and Sulfuric Acid Stratospheric Mimic Systems Nicholas Minogue, Eoin Riordan, and John R. Sodeau pp 4436 - 4444; Nanosecond Laser Photolysis of Ni(II) Tetraphenylporphyrin. Kinetic Studies on Association and Dissociation of Aliphatic Amines at the Axial Positions Hiroyuki Suzuki, Haruna Adachi, Yoshio Miyazaki, and Mikio Hoshino pp 4445 - 4451; Reaction-Diffusion Patterns of the Chlorite-Tetrathionat System in a Conical Geometry Fabienne Gauffre, Vincent Labrot, Jacques Boissonade, Patrick De Kepper, and Etiennette Dulos pp 4452 - 4456; Cavity Ring-Down Spectroscopy of the Benzyl Radical Kenichi Tonokura and Mitsuo Koshi pp 4457 - 4461; Reduction of Substituted Benzenediazonium Salts by Hydrogen Atoms in Aqueous Acidic Solution Studied by Pulse Radiolysis Kim Daasbjerg and Knud Sehested pp 4462 - 4469; Experimental and Computational Study of the Kinetics of OH + Pyridine and Its Methyl- and Ethyl-Substituted Derivatives Laurence Y. Yeung and Matthew J. Elrod pp 4470 - 4477; Is Bimolecular Reduction of Hg(II) Complexes Possible in Aqueous Systems of Environmental Importance Katarina Ga*rdfeldt and Mats Jonsson pp 4478 - 4482;
MOLECULAR STRUCTURE, BONDING, QUANTUM CHEMISTRY, AND GENERAL THEORY
The Pitzer Free Rotor Model for Nondegenerate Modes: Application to the Long-Range Behavior of Halogen Radical Reactions with Substituted Olefins Mohamed Kharroubi and Pascal de Sainte Claire pp 4483 - 4489; Variational Transition-State Theory Rate Constant Calculations of the OH + CH3SH Reaction and Several Isotopic Variants Laura Masgrau, A`ngels Gonza'lez-Lafont, and Jose' M. Lluch pp 4490 - 4496; Low-Temperature Fluorination of Silica by a Nonaqueous Solution of NH4F R. M. Barabash, V. N. Zaitsev, T. V. Kovalchuk, H. Sfihi, and J. Fraissard pp 4497 - 4505; Structure and Stability of M-CO, M = First-Transition-Row Metal: An Application of Density Functional Theory and Topological Approaches Julien Pilme, Bernard Silvi, and Mohammad Esmail Alikhani pp 4506 - 4514; Modeling Complexes of the Uranyl Ion UO2L2n+: Binding Energies, Geometries, and Bonding Analysis Carine Clavague'ra-Sarrio, Sophie Hoyau, Nina Ismail, and Colin J. Marsden pp 4515 - 4525; Is the Hydrogen Atomic Charge Representative of the Acidity of Parasubstituted Phenols? Mari'a de L. Romero and Francisco Me'ndez pp 4526 - 4530; Structures, Intramolecular Rotation Barriers, and Thermochemical Properties of Methyl Ethyl, Methyl Isopropyl, and Methyl tert-Butyl Ethers and the Corresponding Radicals Chiung-Chu Chen and Joseph W. Bozzelli pp 4531 - 4546; Molecular Structure and Infrared Spectra of 4-Fluorophenol: A Combined Theoretical and Spectroscopic Study Wiktor Zierkiewicz, Danuta Michalska, Bogus wa Czarnik-Matusewicz, and Maria Rospenk pp 4547 - 4554; Mechanism of Cis-to-Trans Isomerization of Azobenzene: Direct MD Study Tsutomu Ikegami, Noriyuki Kurita, Hideo Sekino, and Yasuyuki Ishikawa pp 4555 - 4562; Comparative Study of Molecular Mechanics and Theoretical Conformational Analysis of a New 16-Crown-5 Ether via X-ray Crystallography and NMR Spectroscopy Chia-Ching Su, Li-Hwa Lu, and Lilian Kao Liu pp 4563 - 4567; Computational Analysis of Mo and W Oxoanions through Bond Order and Bonding Energy Approaches Adam J. Bridgeman and Germa'n Cavigliasso pp 4568 - 4577; Ester Hydrolysis Rate Constant Prediction from Quantum Topological Molecular Similarity Descriptors U. A. Chaudry and P. L. A. Popelier pp 4578 - 4582;