Journal of Physical Chemistry, 2002, V 106, N 46, November 21.


ARTICLES

DYNAMICS AND RELAXATION
Thermal Fluctuations of the Unusually Symmetric and Stable Superoxide Tetrahydrate Complex: An ab Initio Molecular Dynamics Study I-Feng W. Kuo and Douglas J. Tobias pp 10969 - 10976; A Direct ab Initio Trajectory Study on the Gas-Phase SN2 Reaction OH- + CH3Cl CH3OH + Cl- Hiroto Tachikawa, Manabu Igarashi, and Teruo Ishibashi pp 10977 - 10984; Photoprocesses of Thiacarbocyanine Monomers, Dimers, and Aggregates Bound to Polyanions Tatyana D. Slavnova, Alexander K. Chibisov, and Helmut Gorner pp 10985 - 10990; Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene- Based Dyads with Short Linkage Kei Ohkubo, Hiroshi Imahori, Jianguo Shao, Zhongping Ou, Karl M. Kadish, Yihui Chen, Gang Zheng, Ravindra K. Pandey, Mamoru Fujitsuka, Osamu Ito, and Shunichi Fukuzumi pp 10991 - 10998;
SPECTROSCOPY, GASEOUS CLUSTERS, AND MOLECULAR BEAMS
High Overtones of the C-H Stretching Vibrations in Anisole and Thioanisole Cristina Gellini, Laura Moroni, and Maurizio Muniz-Miranda pp 10999 - 11007; Vibrational Raman and Raman Optical Activity Spectra of -Lactic Acid, -Lactate, and -Glyceraldehyde: Ab Initio Calculations Magdalena Pecul, Antonio Rizzo, and Jerzy Leszczynski pp 11008 - 11016; Photodissociation of Propylene Sulfide at 193 nm: A Photofragment Translational Spectroscopy Study with VUV Synchrotron Radiation Fei Qi and Arthur G. Suits pp 11017 - 11024; A Gaussian-3 Study of the Photodissociation Channels of Propylene Sulfide Justin Kai-Chi Lau, Wai-Kee Li, Fei Qi, and Arthur G. Suits pp 11025 - 11028; Hydrogen-Atom Tunneling of 2,5-Dichloro-3,6-dihydroxy-1,4-benzoquinone in a Low- Temperature Argon Matrix Studied by FTIR Spectroscopy Nobuyuki Akai, Satoshi Kudoh, Masao Takayanagi, and Munetaka Nakata pp 11029 - 11033; Temperature-Independent Rate of Electron-Transfer between a Cobalt(II) and a Ruthenium(III) of Doublet Electronic Configuration Hiroaki Torieda, Akio Yoshimura, Koichi Nozaki, Satomi Sakai, and Takeshi Ohno pp 11034 - 11044; Delayed Fluorescence and Phosphorescence from Polyphenylquinoxalines A. Hayer, H. Bassler, B. Falk, and S. Schrader pp 11045 - 11053; Investigation of Interporphyrin Charge Resonance of Dihedral Angle Controlled Porphyrin Dimers by Resonance Raman Spectroscopy and MO Approaches Dae Hong Jeong, Sung Moon Jang, In-Wook Hwang, Dongho Kim, Naoya Yoshida, and Atsuhiro Osuka pp 11054 - 11063; Absorption Spectrum of Singlet Oxygen (a1g b1g+) in D2O: Enabling the Test of a Model for the Effect of Solvent on Oxygen's Radiative Transitions Lars Klembt Andersen and Peter R. Ogilby pp 11064 - 11069; A New Electronic State of Aniline Observed in the Transient IR Absorption Spectrum from S1 in a Supersonic Jet Takayuki Ebata, Chika Minejima, and Naohiko Mikami pp 11070 - 11074;
KINETICS; ATMOSPHERIC AND ENVIRONMENTAL PHYSICAL CHEMISTRY
Temperature-Dependent Rate and Equilibrium Constants for Br(aq) + Br-(aq) Br2-(aq) Yong Liu, Andre S. Pimentel, Yasuko Antoku, Brent J. Giles, and John R. Barker pp 11075 - 11082; Measurement of Condensed-Phase Reaction Kinetics in the Aerosol Phase Using Single Particle Mass Spectrometry R. Mahadevan, D. Lee, H. Sakurai, and M. R. Zachariah pp 11083 - 11092; Kinetics of the NCN Radical Randall E. Baren and John F. Hershberger pp 11093 - 11097; Reduction of Substituted Benzenediazonium Salts by Solvated Electrons in Aqueous Neutral Solution Studied by Pulse Radiolysis Kim Daasbjerg and Knud Sehested pp 11098 - 11106; Spectroscopy of Hydrothermal Reactions 22. The Effects of Cations on the Decarboxylation Kinetics of Trifluoroacetate, Cyanoacetate, Propiolate, and Malonate Ions Davide Miksa, Jun Li, and Thomas B. Brill pp 11107 - 11114; Unusual Temperature Dependence of Proton Transfer. 2. Excited-State Proton Transfer from Photoacids to Water Boiko Cohen, Pavel Leiderman, and Dan Huppert pp 11115 - 11122; Effects of Metal Ions Distinguishing between One-Step Hydrogen- and Electron- Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin Ikuo Nakanishi, Kentaro Miyazaki, Tomokazu Shimada, Kei Ohkubo, Shiro Urano, Nobuo Ikota, Toshihiko Ozawa, Shunichi Fukuzumi, and Kiyoshi Fukuhara pp 11123 - 11126; Thermochemical Properties of -Hydroxy-Alkoxyl Radicals in Aqueous Solution Gabor Merenyi, Johan Lind, and Sara Goldstein pp 11127 - 11129; Formation and Reaction of Br2- Radicals in the Ionic Liquid Methyltributylammonium Bis(trifluoromethylsulfonyl)imide and in Other Solvents J. Grodkowski and P. Neta pp 11130 - 11134; Rate Coefficients and Products of Ethyl and Vinyl Cross-Radical Reactions Askar Fahr and Dwight C. Tardy pp 11135 - 11140; Missing Thermochemical Groups for Large Unsaturated Hydrocarbons: Contrasting Predictions of G2 and CBS-Q Raman Sumathi and William H. Green Jr. pp 11141 - 11149; Photochemistry of CH2BrCl: An ab Initio and Dynamical Study Tamas Rozgonyi and Leticia Gonzalez pp 11150 - 11161;
MOLECULAR STRUCTURE, BONDING, QUANTUM CHEMISTRY, AND GENERAL THEORY
The Molecular Structures, Energetics, and Nature of Interactions in Arn-N2H+ (n = 1-12) Complexes Yinghong Sheng, Robert W. Gora, Szczepan Roszak, Malgorzata Kaczorowska, and Jerzy Leszczynski pp 11162 - 11167; A Computational Study of the Isomerization of Prolyl Amides As Catalyzed by Intramolecular Hydrogen Bonding Kathryn N. Rankin and Russell J. Boyd pp 11168 - 11172; Experimental and Computational Thermochemistry of 2- and 3-Thiophenecarboxylic Acids Manuel Temprado, Maria Victoria Roux, Pilar Jimenez, Juan Z. Davalos, and Rafael Notario pp 11173 - 11180; Reactivity of HNC with Small Hydrocarbon Radicals Simon Petrie pp 11181 - 11189; Theoretical Study of Microscopic Solvation of Ammonia in Water Clusters: NH3(H2O)n, n = 3, 4 Daniel E. Bacelo pp 11190 - 11196; Computational Probes into the Basis of Silver Ion Chromatography. II. Silver(I)- Olefin Complexes Jose Kaneti, Louis C. P. M. de Smet, Remko Boom, Han Zuilhof, and Ernst J. R. Sudholter pp 11197 - 11204; Theoretical Study on the Alkaline and Neutral Hydrolysis of Succinimide Derivatives in Deamidation Reactions F. Aylin Konuklar, Viktorya Aviyente, and Manuel F. Ruiz Lopez pp 11205 - 11214; ( Counterion Effects on the Cation- Interaction between Alkaline Earth Cations and Benzene Yu-Hui Cheng, Lei Liu, Yao Fu, Rong Chen, Xiao-Song Li, and Qing-Xiang Guo pp 11215 - 11220; Partially Charged H5O2 as a Chemical Switch: A Bond Order and Atoms in Molecules Study of Hydrogen Bonding Determined by Surrounding Groups Michael E. Green pp 11221 - 11226; A Density Functional Study of the Claisen Rearrangement of Allyl Aryl Ether, Allyl Arylamine, Allyl Aryl Thio Ether, and a Series of Meta-Substituted Molecules through Reactivity and Selectivity Profiles Badhin Gomez, Pratim K. Chattaraj, E. Chamorro, R. Contreras, and P. Fuentealba pp 11227 - 11233; Theoretical Study of the 67Zn Electric-Field-Gradient Tensors in Zinc(II) Coordination Complexes Ramsey Ida and Gang Wu pp 11234 - 11239; Are Hydrogen Bonds Unique among Weak Interactions in Their Ability to Mediate Electronic Coupling? Emily Cukier, Sarah Daniels, Eric Vinson, and Robert J. Cave pp 11240 - 11247; Dehalogenation of 5-Halouracils after Low Energy Electron Attachment: A Density Functional Theory Investigation Xifeng Li, Leon Sanche, and Michael D. Sevilla pp 11248 - 11253; Theoretical Study of 9---Erythrofuranosyladenine and Corresponding Carbocyclic Analogues. Evidence for a Base-Activated Conformational Lock Akin Akda, Cynthia M. Carver, Michael L. McKee, and Stewart W. Schneller pp 11254 - 11261; Electron Delocalization in Atomic and Molecular Systems Petar M. Mitrasinovic pp 11262 - 11270; Thermochemistry of Chlorine Fluorides ClFn, n = 1-7, and Their Singly Charged Cations and Anions: A Gaussian-3 and Gaussian-3X Study Chi-Kin Law, Siu-Hung Chien, Wai-Kee Li, and Yu-San Cheung pp 11271 - 11276; Structure and Thermodynamics of Uranium(VI) Complexes in the Gas Phase: A Comparison of Experimental and ab Initio Data Timofei Privalov, Bernd Schimmelpfennig, Ulf Wahlgren, and Ingmar Grenthe pp 11277 - 11282; HOMO-LUMO Gap as an Index of Molecular Size and Structure for Polycyclic Aromatic Hydrocarbons (PAHs) and Asphaltenes: A Theoretical Study. I Yosadara Ruiz-Morales pp 11283 - 11308; Kinetics and Mechanism of the OH + C6H6 Reaction: A Detailed Analysis with First-Principles Calculations I. V. Tokmakov and M. C. Lin pp 11309 - 11326; First Principles Examination of the Acetylene-Water Clusters, HCCH-(H2O)x, x = 2, 3, and 4 Demeter Tzeli, Aristides Mavridis, and Sotiris S. Xantheas pp 11327 - 11337; Interaction of Water Molecules with Cytosine Tautomers: An Excited-State Quantum Chemical Investigation M. K. Shukla and Jerzy Leszczynski pp 11338 - 11346; Exploring the Mechanism for the Synthesis of Silsesquioxanes. 3. The Effect of Substituents and Water Takako Kudo and Mark S. Gordon pp 11347 - 11353; A Theoretical Investigation of the Ground and Excited States of Selected Ru and Os Polypyridyl Molecular Dyes Jean-Francois Guillemoles, Vincenzo Barone, Laurent Joubert, and Carlo Adamo pp 11354 - 11360; Valence Bond Modeling of Barriers in the Nonidentity Hydrogen Abstraction Reactions, X' + H-X X'-H + X (X' X = CH3, SiH3, GeH3, SnH3, PbH3) Lingchun Song, Wei Wu, Kunming Dong, Philippe C. Hiberty, and Sason Shaik pp 11361 - 11370; Many Reactive Fullerenes Tend To Form Stable Metallofullerenes Jun-ichi Aihara pp 11371 - 11374; ( Determination of 13C Chemical Shift Tensors in the Presence of Hydrogen Bonding and 14N Quadrupolar Coupling: p-Aminosalicylic Acid, Isoniazid, and Pyrazinamide Dewey H. Barich, Jacalyn S. Clawson, Dirk Stueber, Mark Strohmeier, Ronald J. Pugmire, and David M. Grant pp 11375 - 11379; Comparative Study on the Interaction of Scandium and Copper Atoms with Small Silicon Clusters Chuanyun Xiao, Ashley Abraham, Reginald Quinn, Frank Hagelberg, and William A. Lester, Jr. pp 11380 - 11393;
GENERAL PHYSICAL CHEMISTRY
Comparative Analysis of Packet and Trigger Waves Originating from a Finite Wavelength Instability Vladimir K. Vanag and Irving R. Epstein pp 11394 - 11399; Excited-State Properties of the Four Stereoisomers of 1-(9-Anthryl)-4-phenyl- 1,3-butadiene: Evidence of Adiabatic and Diabatic Deactivation Pathways G. Bartocci, E. Marri, and A. Spalletti pp 11400 - 11407; Heavy Ion Radiolysis of Liquid Benzene Jay A. LaVerne and M. S. Araos pp 11408 - 11413;
ADDITIONS AND CORRECTIONS

Biography of G. Wilse Robinson Graham R. Fleming, Steven D. Colson, and Edward L.Quitevis: pp 11414 - 11414;