The Journal of Chemical Physics, 2003, V 118, N 5, 1 February.


COMMUNICATIONS

Controlling molecular ground-state dissociation by optimizing vibrational ladder climbing T. Witte, T. Hornung, L. Windhorn, D. Proch, R. de Vivie-Riedle, M. Motzkus, and K. L. Kompa pp. 2021-2024
ARTICLES

Theoretical Methods and Algorithms
A concerted variational strategy for investigating rare events Daniele Passerone, Matteo Ceccarelli, and Michele Parrinello pp. 2025-2032 Computation of molecular Hartree-Fock Wigner intracules Nicholas A. Besley, Darragh P. O'Neill, and Peter M. W. Gill pp. 2033-2038 Continuum description of solvent dielectrics in molecular-dynamics simulations of proteins Bernhard Egwolf and Paul Tavan pp. 2039-2056 A new concise expression for the free energy of a reaction coordinate Ju"rgen Schlitter and Marco Kla"hn pp. 2057-2060 Locally coupled coherent states and Herman-Kluk dynamics M. S. Child and D. V. Shalashilin pp. 2061-2071 Gradient-free and gradient-dependent approximations in the total energy bifunctional for weakly overlapping electron densities Tomasz A. Wesolowski and Fabien Tran pp. 2072-2080 Equivalent core model: Extended theory and applications Nikolai V. Kryzhevoi, Nickolay V. Dobrodey, and Lorenz S. Cederbaum pp. 2081-2091
Gas Phase Dynamics and Structure: Spectroscopy, Molecular Interactions, Scattering, and Photochemistry
Time-dependent interplay between electron emission and fragmentation in the interatomic Coulombic decay S. Scheit, L. S. Cederbaum, and H.-D. Meyer pp. 2092-2107 Photoelectron spectroscopy of Ti [n-] clusters (n=1-130) Shu-Rong Liu, Hua-Jin Zhai, Miguel Castro, and Lai-Sheng Wang pp. 2108-2115 Structural and electronic properties of small titanium clusters: A density functional theory and anion photoelectron spectroscopy study Miguel Castro, Shu-Rong Liu, Hua-Jin Zhai, and Lai-Sheng Wang pp. 2116-2123 Spectroscopically determined potential energy surface of H216O up to 25 000 cm-1 Sergei V. Shirin, Oleg L. Polyansky, Nikolai F. Zobov, Paolo Barletta, and Jonathan Tennyson pp. 2124-2129 The reaction HCl+ + CF4 [-->] HCF [4+] + Cl: Implications for the heat of formation of CF [3+] Eldon E. Ferguson, Thomas M. Miller, and A. A. Viggiano pp. 2130-2134 Semiclassical calculation of thermal rate constants in full Cartesian space: The benchmark reaction D + H2 [-->] DH + H Takeshi Yamamoto and William H. Miller pp. 2135-2152 Absolute total and partial cross sections for the electron impact ionization of diborane (B2H6) R. Basner, M. Schmidt, and K. Becker pp. 2153-2158 Bond-forming reactions of dications: Production of ArO+ and ArO2+ in the reaction of Ar2+ with O2 Daniela Ascenzi, Pietro Franceschi, Paolo Tosi, Davide Bassi, Malgorzata Kaczorowska, and Jeremy N. Harvey pp. 2159-2163 Oxygen isotopic fractionation during UV and visible light photodissociation of ozone Subrata Chakraborty and S. K. Bhattacharya pp. 2164-2172 The excited electronic state of the silver-ammonia complex Jun Miyawaki and Ko-ichi Sugawara pp. 2173-2179 Ferromagnetic spin coupling in the manganese trimer ion evidenced by photodissociation spectroscopy Akira Terasaki, Tina M. Briere, Maria Kulawik, Shinichirou Minemoto, Kensuke Tono, Akira Matsushita, and Tamotsu Kondow pp. 2180-2185 Quantal study of the exchange reaction for N + N2 using an ab initio potential energy surface Dunyou Wang, James R. Stallcop, Winifred M. Huo, Christopher E. Dateo, David W. Schwenke, and Harry Partridge pp. 2186-2189 Optical spectroscopy of jet-cooled NiSi Ned F. Lindholm, Dale J. Brugh, Gretchen K. Rothschopf, Shane M. Sickafoose, and Michael D. Morse pp. 2190-2196 Hydrogen molecular ion and molecule in two dimensions S. H. Patil pp. 2197-2205 Inelastic collision cross sections of CH(X 2 [Pi] ) with He(1S) on new ab initio surfaces D. Ben Abdallah, N. Jaidane, Z. Ben Lakhdar, A. Spielfiedel, and N. Feautrier pp. 2206-2213 The asymmetric dimer N2-O2: Characterization of the potential energy surface and quantum mechanical calculation of rotovibrational levels V. Aquilanti, M. Bartolomei, E. Carmona-Novillo, and F. Pirani pp. 2214-2222 Decay dynamics of the vibrationally activated OH-CO reactant complex Bethany V. Pond and Marsha I. Lester pp. 2223-2234 Characterization of the [X-tilde ] 2A1 (0,0,0) ground vibronic state of CH [2+] by pulsed-field-ionization zero-kinetic-energy photoelectron spectroscopy S. Willitsch and F. Merkt pp. 2235-2241 A monomers-in-dimers model for carboxylic acid dimers Corinna Emmeluth, Martin A. Suhm, and David Luckhaus pp. 2242-2255
Condensed Phase Dynamics, Structure, and Thermodynamics: Spectroscopy, Reactions, and Relaxation
Quantification of order in the Lennard-Jones system Jeffrey R. Errington, Pablo G. Debenedetti, and Salvatore Torquato pp. 2256-2263 Thermodynamically consistent equation of state of hard sphere fluids Byung Chan Eu and Young Gie Ohr pp. 2264-2269 Orientational relaxation and vibrational excitation transfer in methanol-carbon tetrachloride solutions K. J. Gaffney, I. R. Piletic, and M. D. Fayer pp. 2270-2278 Solute-structure dependence of solvation dynamics studied by reference interaction-site model theory Katsura Nishiyama, Fumio Hirata, and Tadashi Okada pp. 2279-2285 Association in a four-coordinated, water-like fluid Travis B. Peery and Glenn T. Evans pp. 2286-2300 Determination of the conditional association constants from the sound velocity data in binary liquid mixtures Jacek Glinski pp. 2301-2307 The cohesive energetics of solid cesium chloride N. C. Pyper pp. 2308-2324 13C-1H dipolar-driven 13C-13C recoupling without 13C rf irradiation in nuclear magnetic resonance of rotating solids K. Takegoshi, Shinji Nakamura, and Takehiko Terao pp. 2325-2341 Quasisaddles of liquids: Computational study of a bulk Lennard-Jones system Pooja Shah and Charusita Chakravarty pp. 2342-2348
Surfaces, Interfaces, and Materials
Mechanism of linear and nonlinear optical effects of KDP and urea crystals Zheshuai Lin, Zhizhong Wang, Chungtian Chen, and Ming-Hsien Lee pp. 2349-2356 Eley-Rideal reactions of H atoms with Cl adsorbed on Au(111): Quantum and quasiclassical studies Joseph G. Quattrucci, Bret Jackson, and Didier Lemoine pp. 2357-2366 Diffusion-controlled reactions with a binding site hidden in a channel Leonardo Dagdug, Alexander Berezhkovskii, Sergey M. Bezrukov, and George H. Weiss pp. 2367-2373
Polymers, Biopolymers, and Complex Systems
Solution effects and the order of the helix-coil transition in polyalanine Yong Peng, Ulrich H. E. Hansmann, and Nelson A. Alves pp. 2374-2380 Non-Gaussian dynamics from a simulation of a short peptide: Loop closure rates and effective diffusion coefficients John J. Portman pp. 2381-2391 An effective-colloid pair potential for Lennard-Jones colloid-polymer mixtures Orlando Guzma'n and Juan J. de Pablo pp. 2392-2397 Dynamics of deterministic fractal polymer networks: Hydrodynamic interactions and the absence of scaling A. Jurjiu, Th. Koslowski, and A. Blumen pp. 2398-2404 Atomic scale fractal dimensionality in proteins Duccio Medini and Allan Widom pp. 2405-2410 Chain orientation and slow dynamics in elastomers by mixed magic-Hahn echo decays R. Fechete, D. E. Demco, and B. Blu"mich pp. 2411-2421 Macroscopic dynamics of ferronematics E. Jarkova, H. Pleiner, H.-W. Mu"ller, and H. R. Brand pp. 2422-2430 A density-functional theory for polymer liquids based on the interaction site model Tomonari Sumi and Fumio Hirata pp. 2431-2442
LETTERS TO THE EDITOR

Notes
Optical four wave mixing spectroscopy for multilevel systems coupled to multimode Brownian oscillators Jaeyoung Sung and Robert J. Silbey pp. 2443-2445
Errata
Erratum: "Theory of solutions in the energy representation. II. Functional for the chemical potential" [J. Chem. Phys. 117, 3605 (2002)] Nobuyuki Matubayasi and Masaru Nakahara p. 2446