The Journal of Chemical Physics, 2003, V 118, N 20, May 22.


COMMUNICATIONS

Electric-field effects of two-level systems observed with single-molecule spectroscopy M. Bauer and L. Kador pp. 9069-9072 Photoelimination of C2H2 and H2 from styrene at 193 nm Ya-Rong Lee, Cheng-Chu Chen, and Shen-Maw Lin pp. 9073-9076 The vacuum ultraviolet photochemistry of the allyl radical investigated using synchrotron radiation T. Schu"?ler, H.-J. Deyerl, S. Du"mmler, I. Fischer, C. Alcaraz, and M. Elhanine pp. 9077-9080 Determining the curvature dependence of surface tension Dimo Kashchiev pp. 9081-9083
ARTICLES

Theoretical Methods and Algorithms
A spin-complete version of the spin-flip approach to bond breaking: What is the impact of obtaining spin eigenfunctions? John S. Sears, C. David Sherrill, and Anna I. Krylov pp. 9084-9094 Improved second- M?ller–Plesset perturbation theory by separate scaling of parallel- and antiparallel-spin pair correlation energies Stefan Grimme pp. 9095-9102 Trajectory-dependent cellularized frozen Gaussians, a new approach for semiclassical dynamics: Theory and application to He–naphtalene eigenvalues Sybil M. Anderson, Daniel Neuhauser, and Roi Baer pp. 9103-9108 Microscopic derivation of hydrodynamic equations for phase-separating fluid mixtures Pep Espan~ol and Cedric Thieulot pp. 9109-9127 Linear scaling computation of the Fock matrix. VI. Data parallel computation of the exchange-correlation matrix Chee Kwan Gan and Matt Challacombe pp. 9128-9135 Fast evaluation of the Coulomb potential for electron densities using multipole accelerated resolution of identity approximation Marek Sierka, Annika Hogekamp, and Reinhart Ahlrichs pp. 9136-9148 A novel method for the solution of the Schro"dinger equation in the presence of exchange terms George H. Rawitscher, S.-Y. Kang, and I. Koltracht pp. 9149-9156
Gas Phase Dynamics and Structure: Spectroscopy, Molecular Interactions, Scattering, and Photochemistry
Structural study of the hydrogen-bonded 1-naphthol·(NH3)2 cluster Christian Tanner, Debora Henseler, Samuel Leutwyler, Leslie L. Connell, and Peter M. Felker pp. 9157-9166 Polarization propagator calculations of the polarizability tensor at imaginary frequencies and long-range interactions for the noble gases and n-alkanes Patrick Norman, Auayporn Jiemchooroj, and Bo E. Sernelius pp. 9167-9174 Ab initio potential-energy surfaces for the [X-tilde ] 2B1, A~ 2A1, and [B-tilde ] 2B2 states of the H2S + molecular ion David M. Hirst pp. 9175-9184 Studies on the photodissociation and symmetry of SO [2+] ( [D-tilde] ) Limin Zhang, Zhong Wang, Jiang Li, Feng Wang, Shilin Liu, Shuqin Yu, and Xingxiao Ma pp. 9185-9191 Photoelectron imaging of carbonyl sulfide cluster anions: Isomer coexistence and competition of excited-state decay mechanisms Eric Surber and Andrei Sanov pp. 9192-9200 On the electronic structure of CmFn (n = 1–4) by all-electron Dirac–Hartree–Fock calculations Yuji Mochizuki and Hiroshi Tatewaki pp. 9201-9207 Single-pulse coherent anti-Stokes Raman spectroscopy in the fingerprint spectral region Nirit Dudovich, Dan Oron, and Yaron Silberberg pp. 9208-9215 A dynamical definition of quasibound molecular clusters Sarah A. Harris and Ian J. Ford pp. 9216-9223 Theoretical studies of the first-row transition metal phosphides Glenna S. M. Tong, G. H. Jeung, and A. S-C. Cheung pp. 9224-9232 Rydberg–valence interactions in CH2Cl [-->] CH2 + Cl photodissociation: Dependence of absorption probability on ground state vibrational excitation Sergey V. Levchenko, Andrei V. Demyanenko, Vladimir L. Dribinski, Aaron B. Potter, Hanna Reisler, and Anna I. Krylov pp. 9233-9240 Ag3 Born–Oppenheimer potential hypersurfaces Yinghau Shen and Joseph J. BelBruno pp. 9241-9246 Dispersed fluorescence spectroscopy of AlNi, NiAu, and PtCu Jacqueline C. Fabbi, Lars Karlsson, Jon D. Langenberg, Quinton D. Costello, and Michael D. Morse pp. 9247-9256 Density functional and Monte Carlo studies of sulfur. I. Structure and bonding in Sn rings and chains (n = 2–18) R. O. Jones and P. Ballone pp. 9257-9265 Quantum dynamics study of isotope effect for H + CH4 reaction using the SVRT model Xin Zhang, Guang-Hui Yang, Ke-Li Han, M. L. Wang, and John Z. H. Zhang pp. 9266-9271 The ultrafast dynamics of HBr–water clusters: Influences on ion-pair formation S. M. Hurley, T. E. Dermota, D. P. Hydutsky, and A. W. Castleman, Jr. pp. 9272-9277 The microwave spectrum, ab initio analysis, and structure of the fluorobenzene–hydrogen chloride complex M. Eugenia Sanz, Sonia Antoli'nez, Jose' L. Alonso, Juan C. Lo'pez, Robert L. Kuczkowski, Sean A. Peebles, Rebecca A. Peebles, Faith C. Boman, Elfi Kraka, and Dieter Cremer pp. 9278-9290
Condensed Phase Dynamics, Structure, and Thermodynamics: Spectroscopy, Reactions, and Relaxation
Dielectric constant and proton and dis in ice Ih: Monte Carlo computer simulations Steven W. Rick and A. D. J. Haymet pp. 9291-9296 Short-time kinetics of an irreversible bimolecular solution reaction: Asymptotic prediction by a non-Markovian Smoluchowski approach Wolfgang Naumann pp. 9297-9302 Dynamics in supercooled liquids and in the isotropic phase of liquid crystals: A comparison Hu Cang, Jie Li, V. N. Novikov, and M. D. Fayer pp. 9303-9311 Theory of single molecule line shapes of multichromophoric macromolecules Seogjoo Jang and Robert J. Silbey pp. 9312-9323 Single complex line shapes of the B850 band of LH2 Seogjoo Jang and Robert J. Silbey pp. 9324-9336 Kinetic extensions of the nucleation theorem Robert McGraw and David T. Wu pp. 9337-9347 Spectral relaxation in pump–probe transients Darcie A. Farrow, Anchi Yu, and David M. Jonas pp. 9348-9356 Critical behavior of dielectric permittivity and electric conductivity in temperature and pressure studies above and below the critical consolute point P. Malik, S. J. Rzoska, A. Drozd-Rzoska, and J. Jadzyn pp. 9357-9363
Surfaces, Interfaces, and Materials
Two-vibron bound states in CO/Ru(001): An effective Hamiltonian approach V. Pouthier pp. 9364-9371 Lattice-gas study of the kinetics of the catalytic NO–CO reaction on rhodium surfaces. II. The effect of nitrogen surface islands V. Bustos, R. Un~ac, F. Zaera, and G. Zgrablich pp. 9372-9379 Exciton–bath coupling and inhomogeneous broadening in the optical spectroscopy of semiconductor quantum dots Mayrose R. Salvador, Margaret A. Hines, and Gregory D. Scholes pp. 9380-9388 Liquids in confined geometry: How to connect changes in the structure factor to modifications of local Denis Morineau and Christiane Alba-Simionesco pp. 9389-9400
Polymers, Biopolymers, and Complex Systems
Microstructure of nematic amorphous block copolymers: Dependence on the nematic volume fraction M. Hamm, G. Goldbeck-Wood, A. V. Zvelindovsky, and J. G. E. M. Fraaije pp. 9401-9419 Ionic conductivity, glass transition, and local free volume in poly(ethylene oxide) electrolytes: Single and mixed ion conductors D. Bamford, A. Reiche, G. Dlubek, F. Alloin, J.-Y. Sanchez, and M. A. Alam pp. 9420-9432 Numerical calculation of the melting phase diagram of low molecular-weight polyethylene Chinmay Das and Daan Frenkel pp. 9433-9440 Tuning of the excited state properties of phenylenevinylene oligomers: A time-dependent density functional theory study F. C. Grozema, R. Telesca, J. G. Snijders, and L. D. A. Siebbeles pp. 9441-9446 Interactions between brush-coated clay sheets in a polymer matrix Rong Wang, Feng Qiu, Hongdong Zhang, and Yuliang Yang pp. 9447-9456
LETTERS TO THE EDITOR

Comments
Comment on "Submillimeter spectroscopic study of concentrated electrolyte solutions as high density plasma" [J. Chem. Phys. 116, 5701 (2002)] V. I. Gaiduk and J. K. Vij pp. 9457-9458
Errata
Erratum: "Simulation of the coexistence of a shearing liquid and a strained crystal" [J. Chem. Phys. 118, 4115 (2003)] Scott Butler and Peter Harrowell p. 9459 Erratum: "Density of states simulations of proteins" [J. Chem. Phys. 118, 4285 (2003)] Nitin Rathore, Thomas A. Knotts IV, and Juan J. de Pablo pp. 9460-9461