THE RARE-ELEMENT-ENRICHED MONZOGRANITE - PEGMATITE - QUARTZ VEIN SYSTEMS IN THE PREISSAC-LACORNE BATHOLITH, QUEBEC. I. GEOLOGY AND MINERALOGY

THOMAS MULJA, ANTHONY E. WILLIAMS-JONES, SCOTT A. WOOD* and MICHEL BOILY**
Department of Earth and Planetary Sciences, McGill University, 3450 University Street, Montreal, Quebec H3A 2A7

* Present address: Department of Geology and Geological Engineering, University of Idaho, Moscow, Idaho 83843, U.S.A.
** Present address: Géon, 10785, rue St-Urbain, Montréal, Québec H3L 2V4.


Abstract

The monzogranitic plutons in the Preissac-Lacorne batholith, Quebec, in the Abitibi Greenstone Belt of the Superior Province, display geological and mineralogical features that resemble idealized zoned intrusions and associated rare-element quartz veins and pegmatites. The zoning comprises biotite, two-mica, and muscovite monzogranites; the mineralization in pegmatite-poor plutons is dominated by molybdenite-bearing quartz veins, which are spatially related to the more evolved rocks (i.e., muscovite-bearing monzogranite). In contrast, pegmatite-rich plutons are surrounded by rare-element pegmatites, which vary systematically with distance from the plutons from beryl-bearing through spodumene-beryl-bearing to spodumene-bearing. In addition, Mo-bearing albitite dikes and quartz veins occur beyond the spodumene pegmatites. Mineralogical changes from biotite to muscovite monzogranite are characterized by a decrease in the abundance of oligoclase, biotite, magnetite, monazite, apatite, and zircon, and an increase in the abundance of albite, muscovite and garnet. The mineralogical trend continues into the pegmatites, which are composed of albite, K- feldspar, quartz, muscovite (biotite is absent), garnet, beryl, spodumene, molybdenite, and columbite-tantalite. The major- element chemistry of the rock-forming minerals changes progressively from biotite through two-mica to muscovite monzogranite; plagioclase compositions vary from An13<0150>17 to An6, and the Fe/(Fe + Mg) of biotite and muscovite increases from 0.7 to 0.85 and from 0.65 to 0.85, respectively. This mineral-chemical evolution extends into the pegmatites; the plagioclase in these rocks is almost pure albite (An1-5), and muscovite is lower in Fe/(Fe + Mg) and richer in Al than that in the muscovite monzogranite. Concentrations of Cs, Ta, and Rb in muscovite increase, whereas that of Sc decreases, from the muscovite monzogranite to the rare-metal pegmatites. The systematic mineralogical evolution and mineral-chemical trends, and the field relationships of the monzogranites, are interpreted to indicate that the various subtypes of monzogranite were produced mainly by fractional crystallization of biotite monzogranitic magma. Further differentiation of the fractionated monzogranitic melts produced rare-element pegmatites.


Keywords: rare-element monzogranite, beryl pegmatite, spodumene pegmatite, mineralogy, mineral chemistry, Preissac- Lacorne batholith, Quebec.